File:Butane-2D-flat.png
Acyclic aliphatic compound (Butane)
File:Cyclobutane2.svg
Cyclic aliphatic compound (Cyclobutane)

In organic chemistry, aliphatic compounds (11px /ˌælɨˈfætɨk/; G. aleiphar, fat, oil) are acyclic or cyclic, non-aromatic carbon compounds.[1] Thus, aliphatic compounds are opposite to aromatic compounds.

Structure

In aliphatic compounds, carbon atoms can be joined together in straight chains, branched chains, or non-aromatic rings (in which case they are called alicyclic). Aliphatic compounds can be saturated, joined by single bonds (alkanes), or unsaturated, with double bonds (alkenes) or triple bonds (alkynes). Besides hydrogen, other elements can be bound to the carbon chain, the most common being oxygen, nitrogen, sulfur, and chlorine.

The simplest aliphatic compound is methane (CH4). Aliphatics include alkanes (e.g. paraffin hydrocarbons), alkenes (e.g. ethylene) and alkynes (e.g. acetylene). Fatty acids consist of an unbranched aliphatic tail attached to a carboxyl group.

Properties

Most aliphatic compounds are flammable, allowing the use of hydrocarbons as fuel, such as methane in Bunsen burners and as Liquified Natural Gas (LNG), and acetylene in welding.

Examples for aliphatic compounds

The most important group of aliphatic compounds are:

  • n-, Iso- and Cyclo-Alkanes (Saturated Hydrocarbons)
  • n-, Iso- and Cyclo-Alkenes and -Alkynes (Unsaturated Hydrocarbons).

Important examples of low-molecular aliphatic compounds can be found in the list below (sorted by the number of carbon-atoms):

Formula Name CAS-Number Structural Formula Chemical Classification
CH4 Methane 74-82-8 75px Alkane
C2H2 Ethyne 74-86-2 75px Alkyne
C2H4 Ethene 74-85-1 75px Alkene
C2H6 Ethane 74-84-0 75px Alkane
C3H4 Propyne 74-99-7 75px Alkyne
C3H6 Propene - 100px Alkene
C3H8 Propane - 100px Alkane
C4H6 1,2-Butadiene 590-19-2 100px Diene
C4H6 1-Butyne - 100px Alkyne
C4H8 Butene - e.g. 100px Alkene
C4H10 Butane - 100px Alkane
C6H10 Cyclohexene 110-83-8 40px Cycloalkene
C5H12 n-pentane 109-66-0 75px Alkane
C7H14 Cycloheptane 291-64-5 50px Cycloalkane
C7H14 Methylcyclohexane 108-87-2 75px Cyclohexane
C8H8 Cubane 277-10-1 75px Cyclobutane
C9H20 Nonane 111-84-2 100px Alkane
C10H12 Dicyclopentadiene 77-73-6 125px Diene, Cycloalkene
C10H16 Phellandrene 99-83-2 50px50px Terpene, Diene Cycloalkene
C10H16 α-Terpinene 99-86-5 30px Terpene, Cycloalkene, Diene
C10H16 Limonene 5989-27-5 50px50px Terpene, Diene, Cycloalkene
C11H24 Undecane 1120-21-4 125px Alkane
C30H50 Squalene 111-02-4 125px Terpene, Polyene
C2nH4n Polyethylene 9002-88-4 75px Alkane

Aliphatic acids

Aliphatic acids are the acids of nonaromatic hydrocarbons, such as acetic, propionic, and butyric acids.

See also

References

  1. Script error
ar:مركب أليفاتي

ca:Hidrocarbur alifàtic cs:Alifatická sloučenina da:Alifatisk forbindelse de:Aliphatische Kohlenwasserstoffe el:Αλειφατική ένωση es:Hidrocarburo alifático fr:Composé aliphatique id:Senyawa alifatik it:Composti alifatici he:אליפטיות hu:Alifás nl:Alifatische verbinding ja:脂肪族化合物 no:Alifatisk forbindelse pl:Związki alifatyczne pt:Composto alifático ru:Алифатические соединения si:ඇලිෆැටික සංයෝග sk:Alifatický uhľovodík sl:Alifatska spojina sr:Alifatično jedinjenje fi:Alifaattinen yhdiste sv:Alifatisk th:สารประกอบแอลิแฟติก uk:Аліфатичні сполуки vi:Hợp chất aliphatic zh:脂肪族化合物