Obsidian hydration dating

Obsidian hydration dating (OHD) is a geochemical method of determining age in either absolute or relative terms of an artifact made of obsidian.

Obsidian is a volcanic glass that was sometimes used as raw material for the manufacture of stone tools such as projectile points, knives, or other cutting tools through the process of flintknapping. Obsidian is too brittle to be used as a pounding (e.g., axe, adze) or grinding tool. Obsidian obeys the property of mineral hydration, and absorbs water when exposed to air. When an unworked nodule of obsidian is initially fractured, there is typically less than 1% water present. Over time, water slowly diffuses into the artifact forming a narrow "band," "rim," or "rind" that can be seen and measured with many different techniques such as a) a high-power microscope with 40-80 power magnification b) depth profiling with SIMS secondary ion mass spectrometry. Experimental and empirical data indicate that this hydration band grows roughly as the square root of time (measured in years). Thus, the hydration rind initially grows quickly, then slows with age.

Measurement

To measure the hydration band with high-power microscope a small slice of material is typically cut from an artifact. This sample is ground down to about 30 micrometers thick and mounted on a petrographic slide. The hydration rind is measured under a high-power microscope outfitted with some method for measuring distance, typically in tenths of micrometers. The technician measures the microscopic amount of water absorbed on freshly broken surfaces. The principle behind obsidian hydration dating is simple–the longer the artifact surface has been exposed, the thicker the hydration band will be.

In case of measuring the hydration rim using the depth profiling ability of the secondary ion mass spectrometry technique, the sample is mounted on a holder without any preparation or cutting. This method of measurement is non-destructive.

In order to use obsidian hydration for absolute dating, the conditions that the sample has been exposed to and its origin must be understood or compared to samples of a known age (e.g. as a result of radiocarbon dating of associated materials).

Several factors complicate simple correlation of obsidian hydration band thickness with absolute age. Temperature is known to speed up the hydration process. Thus, artifacts exposed to higher temperatures, for example by being at lower elevation, seem to hydrate faster. As well, obsidian chemistry, including the intrinsic water content, seems to affect the rate of hydration. Once an archeologist can control for the geochemical signature of the obsidian (e.g., the "source") and temperature (usually approximated using an "effective hydration temperature" or EHT coefficient), he or she may be able to date the artifact using the obsidian hydration technique. Water vapor pressure may also affect the rate of obsidian hydration.

The reliability of the method based on Friedman’s empirical age equation (x\(^2\)=kt, x the hydration rim, k the diffusion coefficient and t the time) is questioned from several grounds regarding temperature dependence, square root of time and determination of diffusion rate per sample and per site, apart of some successful attempts on the procedure and applications. Obsidian hydration dating has been critically assessed by several scientists around world.

Several commercial companies and university laboratories provide obsidian hydration services.

History

Obsidian hydration dating was introduced in 1960 by Irving Friedman and Robert Smith of the U.S. Geological Survey. Their initial work focused on obsidians from archaeological sites in western North America.

In 2002, two independent research teams introduced the use of SIMS (Secondary ion mass spectrometry) in the measurement of the hydration rim.

Also, in 2002, a novel method was developed - the SIMS-SS method. The founder of this method Ioannis Liritzis and his team have made several applications on world artifacts.

Today the technique is applied extensively by archaeologists to date prehistoric sites and sites from protohistory in California and the Great Basin of North America. It has also been applied in South America, the Middle East, the Pacific Islands, including New Zealand and Mediterranean Basin.

See also

• Dating methodology (archaeology)
• Absolute dating
• Relative dating
• Water vapor
• Water vapor feedback

References

• Anovitz, L.M., Elam, M., Riciputi. L., Cole, D., 1999. The failure of obsidian hydration dating: sources, implications, and new directions. Journal of Archaeological Science 26, 735-752
• Liritzis.I and Diakostamatiou.M (2002) Towards a new method of obsidian hydration dating with secondary ion mass spectrometry via a surface saturation layer approach. Medierranean Archaeology & Archaeometry, vol.2, N0 1, 3-20.
• Riciputi, L. R., Elam J.M., Anovitz, L.M., Cole, D.R., 2002. Obsidian diffusion dating by secondary ion mass spectrometry: a test using results from Mound 65, Chalco, Mexico.Journal of Archaeological Science 29, 1055-1075.
• Ambrose, W., Novak, S.W., Abdelrehim, I., 2004. Powdered obsidian for determining hydration rates and site thermometry. Mediterranian Archaeology and Archaeometry 4, 2, 17-31.
• Liritzis.I (2006) SIMS-SS A new obsidian hydration dating method: analysis and theoretical principles. Archaeometry , 48 (3), 533-547.
• Rogers, A. K., 2008. Field data validation of an algorithm for computing obsidian effective hydration temperature. Journal of Archaeological Science 35, 441-447.
• Eerkens, J.W, Vaughn,K.J, Carpenter ,T.R, Conlee ,C.A, Moises Linares Grados , Schreiber,K (2008) Obsidian hydration dating on the South Coast of Peru Journal of Archaeological Science 35, 2231-2239
• Liritzis, I and Laskaris, N (2009) Advances in obsidian hydration dating by secondary ion mass spectrometry: World examples. Nucl. Instr. Meth. In Physics Research B, 267, 144-150.

External links

• National Park Service page describing Obsidian hydrationhe:תיארוך אובסידיאן באמצעות מיום